METHOD FOR PRODUCING A BUILDING PANEL

专利摘要:
composite boards and panels. the invention relates to a building panel (1) including a water resistant core (5) comprising a thermoplastic material (21) and a surface layer (4) comprising thermosetting resins. production methods for forming a board material (1') with a dry mixture of thermoplastic particles (21a) in powder form and fillers in powder form and applying a surface layer (4) with a hot-hot lamination process for a core (5) comprising such board material are also described.
公开号:BR112016021957B1
申请号:R112016021957-0
申请日:2015-03-30
公开日:2021-08-17
发明作者:Darko Pervan
申请人:Ceraloc Innovation Ab；
IPC主号:

专利说明:

Technical Field
[001] The invention relates generally to the field of building panels, preferably floor panels, comprising a mixture of plastic materials in powder form, preferably thermoplastic material and thermosetting resins, and fillers in powder form, preferably fillers based on wood and mineral fillers. Production methods for forming such panels comprising snap systems are also disclosed. Application field
[002] Embodiments of the present invention are particularly suitable for use in floors, which are formed from floor panels comprising a core, a decorative wear-resistant surface layer and preferably a balancing layer on the back side of the core. The following description of the techniques, problems of known technology and objectives and aspects of the invention will therefore be as a non-limiting example, aimed above all at this field of application and in particular for floors which are installed floating with a system of mechanical fitting.
[003] It should be emphasized that embodiments of the invention can be used to produce building panels in general such as, for example, wall panels and furniture components. Background
[004] The following description is used to describe the background and products, materials and production methods that may comprise specific parts of preferred embodiments in the description of this invention. The floor types described below typically have important common features. They are intended to be installed in a floating manner with a mechanical locking system and the decoration is, in most cases, achieved by colored pigments.
[005] The different types of floors described below use two main classes of polymers, thermosetting polymers and thermoplastic polymers, to provide bonding between particles, mainly wood and mineral fillers. Such fillers are used to improve mechanical properties or just as reducers to decrease the amount of polymers used.
[006] Thermosetting polymers are characterized by the fact that they melt, float and polymerize with increased rigidity when heat and pressure are applied. They are completely cured and cannot melt again. Thermoplastic particles, on the other hand, soften and melt when temperature is increased and stiffness increases when they are cooled.
[007] Thermoplastic polymers are very stable to moisture and can be formed as a product comprising only a specific polymeric material. Thermosetting polymers are very sensitive to moisture and very brittle. They need to be combined and reinforced with fibres, usually with wood fibres. 1. Thermosetting floors.
[008] This flooring category is characterized by the fact that thermosetting resins such as, for example, melamine formaldehyde (MF), urea formaldehyde (UF) or phenol formaldehyde (PF) resins are mainly combined with wood fibers and cured under heat and pressure so that separate core layers or surface layers can be formed. a) Laminate floors.
[009] Most all laminate floors feature a wooden design. Such laminate floors have a 6-12mm fiberboard core, a 0.2mm thick laminate top decorative surface layer and a 0.1-0.2mm thick lower balance layer. Decorative and wear properties are usually achieved with two separate layers of melamine formaldehyde-impregnated paper (a decorative layer and a wear layer), one on top of the other. The decorative layer is a printed paper and the wear layer is a clear overlay paper, which comprises small particles of aluminum oxide. The core is usually a high density fiberboard (HDF) comprising wood fibers and a mixture of MF and UF resins. The decorative paper and overlay paper are directly laminated by a hot-hot production method to the HDF core under high heat and pressure (170°C, 40 bar). Hot-hot pressing generally refers to a pressing method where a press table has the final temperature essentially equal to the initial temperature (eg, within about 10°C). Hot-hot pressing has a very low cost as it is not necessary to cool the press table, but it can only be used in direct surface lamination based on high heat curing thermosets which are laminated to core materials very thick comprising thermosetting resins that are capable of absorbing water vapor from core moisture and the surface layer that is created at high pressing temperatures above 100°C.
[0010] A separate laminate sheet can also be produced in a continuous or batch pressing operation and the laminate sheet is then glued to a core material. This gluing, which can be done cold, allows separate laminate sheets to be bonded to different core materials, as long as they have similar moisture movements as the surface layer when the relative humidity (RH) varies between dry conditions (RH 20 %) and moist (RH 90%). b) Powder-based floors.
[0011] Recently, new types of "paperless" floors have been developed with solid surfaces comprising a substantially homogeneous powdery mixture of fibers, binders and wear-resistant particles, hereinafter referred to as WFF ("Wood Fiber Floor") (wood fiber flooring). ).
[0012] The powder mixture may comprise aluminum oxide particles, thermosetting resin such as melamine formaldehyde resins and wood fibers. In most applications, decorative particles such as, for example, colored pigments are included in the mix. In general, all of these materials are applied in dry form as a mixed powder onto a wood-based core such as an HDF core and cured in a hot-hot direct lamination step with heat and pressure similar to those used in laminate flooring. .
[0013] Digital powder printing has already been developed and it is possible to create very advanced designs in wood, stone and tile by injecting drops of water-based ink comprising pigment dispersions in the powder before pressing. A newly developed Binder and Powder (BAP) printing method can also be used to provide a digital print on a powder-based surface. Conventional digital printing methods are divided into two separate steps comprising a separate application of a liquid binder, commonly called "ink white", and dry dyes, commonly called "dry ink". Colored dry paint particles are applied to the surface of a panel. Some particles are bound together by a digitally formed pattern of ink white applied by the printhead. Other unbound dry ink particles are removed and the remaining bound particles form a digital decoration. This two-step process can be repeated and multiple colors of dry ink can be applied so that an advanced, multi-color, high-definition digital print can be formed more cost-effectively. The main advantage is that very simple liquid water-based substances can be used and pigment-based dry ink dyes are very cheap as pigment dispersions are not necessary. 2. Thermoplastic floors
[0014] This flooring category is characterized by the fact that thermoplastic materials such as, for example, polyvinyl chloride (PVC), polypropylene (PP), or polyethylene (PE) are blended with mineral fibers or wood fibers. The final pressing is done at a lower pressure than that generally used, for example, in the production of laminates and with a hot-cold pressing method. The temperature is generally similar, around 140 - 160°C. Thermoplastic material melts at high temperatures and curing does not take place. The press table or belt must therefore be cooled to below 100°C in order for the thermoplastic layer to be converted from a floating paste to a solid layer. Separate thermoplastic layers can be fused or laminated together by heating and cooling under pressure. c) LVT floors
[0015] Luxury vinyl tiles, commonly called LVT floors, are usually constructed as a layered product made of thermoplastic material such as PVC, commonly called vinyl, mixed with mineral fillers, colored pigments and plasticizers. The LVT name is a bit misleading as a large proportion of LVT floors feature a plank size with a wooden design. They can also comprise plastic materials other than vinyl. LVT has become a generic name for high quality resilient floors that can be installed floating with a snap system.
[0016] Thermal molding is used to form the PVC layers. Co-rotating twin-screw extruders are used to produce high quality thermosetting PVC layers with fillers. The screws press and mix the material under heat.
[0017] The extruder can be filled with preformed small plastic pellets comprising a PVC compound, pigments, fillers etc. Compounding is a process where mixing polymers and additives in a molten state under heat and usually also under pressure is used to form plastic pellets comprising a homogeneous mixture of different raw materials. Co-kneaders, twin-screw extruders and internal mixers are the most common compounding devices used in the plastics industry.
[0018] The compounding process can be avoided and an extruder can also be directly filled with basic plastic particles and separate fillers and other additives that are mixed in a hopper attached to the extruder. This method can be used to save material expenses. Advanced twin screw extruders with optimized screw geometry combined with exact temperature control are used to achieve high flux homogeneity.
[0019] The extruder comprises a flat sheet die which provides a slurry of essentially the same width as the finished layer. Die usually have adjustable die nozzles generally controlled by the oil temperature that offer a wide range of thicknesses.
[0020] The melted slurry is further processed with 3-roll polishing calenders comprising a fixed central hot roll and two adjustable rolls on each side for calibration. The first cylinder is hot and the third cylinder is cold. The flux feed angle, which is determined by the weight and elongation of the flux, can be changed by adjusting the position of the first cylinder. Horizontal, slanted or vertical cylinder arrangements can be used.
[0021] A wide range of downstream equipment and methods are used to laminate the layers under heat and pressure and to cool the plastic layers to form a multilayer sheet. A simple method is to cut the layers into sheets and use a hot-cold press with multiple openings. In continuous production, several extruders can be used and the layers are hot when they are laminated together, in most cases with an intermediate layer of fiberglass. Cooling and stabilizing the panel to prevent warping takes up a lot of space and a continuous production line can be several hundred meters long.
[0022] Extruders and calenders can be replaced by continuous double belt presses comprising pressure heating and cooling combined with several spaced rollers. Plastic compounds in the form of pellets are spread over the lower belt and pressed together under heat and pressure. A similar continuous press can also be used to laminate multiple sheets and sheets to form a panel for LVT floors.
[0023] The core is mainly made of several layers comprising PVC mixed with chalk and/or limestone fillers. The most common core materials comprise an intermediate part about 50% limestone and an equilibrium layer about 40% limestone. A lower lime content in the lining is used to balance the high plastic content in the top layer. Some LVT core materials can comprise up to 80% lime loads. These high filler core materials are very brittle and it is difficult to form a tight fit system.
[0024] A 0.1mm high quality decorative PVC sheet is applied over the upper side of the core. A clear vinyl wear layer with a thickness of 0.1 - 0.6 mm is usually applied over the decorative sheet. The base layer, decorative sheet and clear layer are fused or laminated together with heat and pressure in continuous or batch press operations to form a 3-6 mm floor panel. A UV-curable clear polyurethane (PU) lacquer is usually applied as a protective layer over the clear PVC sheet. LVT floors are installed floating with a locking system similar to laminate and powder-based floors.
[0025] The decorative effects are achieved with a decorative foil that is printed separately and cast onto the core layers. The blade comprises a single color that is usually white and covers the dark color of the core. The blade provides a base color for the gravure printing process where special solvent-based inks comprising pigments are used to create designs on wood, tile and stone. d) WPC floors
[0026] Wood and plastic composite (WPC) panels comprising thermoplastic material mixed with wood particles have been used in extruded sections and injection molding in various industries for many years. Recently, WPC floorboards in plank sizes have been developed for outdoor use primarily as an ornament. Thermoplastic material such as PVC or PP is mixed with wood in the form of sawdust or wood chips in an amount of about 50% to 80% by weight (w) of wood particles. Products intended for use in outdoor environments may comprise 50% by weight or less of wood particles. Wood content can exceed 70% by weight in products intended for indoor use. Processing is similar to the methods used to produce an LVT floor. It is possible to use a two-step process where, in a first step, wood fiber particles and plastic particles are mixed together under heat and pressure to form plastic pellets and fed into an extruder. Fibers and plastic granules can also be directly mixed during extrusion. Alternatively, the composite plastic pellets can be spread over a belt and pressed to form WPC sheets in a continuous double belt press comprising a heating section and a cooling section as described above. The decorative properties are mainly achieved by pigments that are included in the wood/plastic mixture. WPC panels can also be printed, painted or veneered. 3. Combi-floor.
[0027] Thermoplastic and thermosetting materials can be combined. Thermoplastic LVT layers can, for example, be glued to an HDF core or a WPC core. Definition of Some Terms
[0028] In the following text, the visible surface of the installed floor panel is called "front side or top side", while the opposite side of the floor panel, facing the subfloor, is called "rear side or underside".
[0029] By "up" is meant facing the front side and by "down" facing the rear side. By "vertically" is meant perpendicular to the surface and by "horizontally" parallel to the surface.
[0030] By "panel" is meant an essentially flat sheet comprising a core and a decorative surface formed on the core.
[0031] By "board" is meant an essentially flat sheet material intended to be covered by a surface layer and used as a core in a panel. Known Technique and its Problems
[0032] The general technologies that were developed by the industry with the aim of improving the properties and cost structures of the floors described above are described below. The methods can be used partially or completely in various combinations with preferred embodiments of the invention to create a board and panel in accordance with this disclosure of the invention.
[0033] The types of floors described above have different properties and cost structures. Laminate and WFF floors have superior surface properties related to wear, impact and stain resistance. The hot-hot direct lamination method is very cost effective. The main disadvantages are that they are hard, sensitive to moisture and offer a high noise level when people walk on the floor.
[0034] LVT floors, on the other hand, are soft, flexible, moisture-proof and silent. However, several properties are inferior to laminate floors. The plastic surface is sensitive to stains and heat and production costs are generally higher than for laminate flooring as hot-cold pressing methods can be used. A panel for LVT floors expands 3 mm/m when the temperature rises from 5 - 65°C.
[0035] The main advantage of WPC floors compared to LVT floors is that the wood fibers in the WPC floor are opposed to thermal expansion. WPC floors are also more rigid and can overcome subfloor defects. However, producing WPC floors is expensive and it is difficult to apply an attractive decor layer that is wear and stain resistant and has proper moisture movement to prevent warping. WPC floors are harder than LVT floors and the noise level is generally higher.
[0036] It is generally easy to form a tight fit system on an HDF core. WPC panels are quite rigid and the interlocking system can have similar or even higher strength compared to HDF based laminate flooring. Forming interlocking systems on an LVT floor is much more complicated due to the fact that the core is thinner and softer. One disadvantage is the fact that the snapping strength of an LVT-based snapping system decreases considerably at higher temperatures as the core gets softer.
[0037] It would be advantageous if a waterproof thermoplastic core with sufficient strength to form a mechanical fit system and favorable moisture and thermal properties could be produced at lower costs and if such a core could be combined with a surface layer of high quality comprising thermosetting resins such as melamine formaldehyde resins. Considerable advantages can be obtained if such a surface layer can be laminated directly with a low cost hot-hot pressing method to form a thermoplastic core.
[0038] A problem that is preferably solved is the shrinkage of the melamine resin that occurs during pressing when the resin cures and after pressing when the panel is cooled to room temperature. These problems are solved when direct lamination is done against a wood-based panel such as HDF and wood particle board comprising thermosetting resins. The problems are not solved when the lamination is done against a core comprising thermoplastic materials.
[0039] Another problem that is preferably solved is that of the different moisture variations of thermosetting materials and thermoplastic materials. As an example, we can mention that a surface layer comprising wood fibers and thermosetting melamine resins can expand about 0.8% when the relative humidity increases from 20 to 90%. The comparable expansion of an HDF core based on thermosetting melamine/urea binders can be around 0.4% and it is possible to overcome this difference with a strong lamination between the wood fibers in the core and the thermosetting resin in the surface layer. The lower moisture movement of the core will counteract the higher moisture movement of the thermosetting material-based surface layer and a laminated panel may have a moisture movement that is an average of the two movements, for example, a moisture movement of about 0.6%.
[0040] Humidity variations of a WPC panel can be as little as 0.05% over a period of time when a melamine formaldehyde layer expands by 0.8%. LVT panels are even more moisture stable and virtually no expansion can be measured. Different moisture movements between a moisture sensitive surface layer comprising, for example melamine laminated to a WPC or moisture stable LVT core comprising thermoplastic material will create high shear forces between the surface layer and the core and this can cause delamination. Furthermore, it is also very difficult and in fact practically impossible to laminate a thermosetting layer with a direct hot-hot lamination method to form a conventional WPC or LVT layer where all fillers are embedded in a thermoplastic layer. Conventional inkjet digital printing and BAP digital printing described above are based on the main principle that ink drops should not float or clump when they hit the surface. It is difficult to use fingerprints on dense, non-absorbent surfaces such as thermoplastic surfaces. It would be quite advantageous if surfaces comprising thermoplastic resins could be formed so that the floating of the ink drops could be avoided.
[0041] WO 96/27721 describes a WPC type of floorboard with a core of wood particles impregnated with a thermoplastic and with a decorative thermosetting laminate as a surface layer glued onto the core. It is difficult to glue a thermosetting material to a thermoplastic WPC core and the document does not provide any description of how the gluing should be done. The materials have different humidity and humidity movements and such panels will warp or the glue layer will break when the relative humidity varies between 20 and 90%.
[0042] EP 1847385 B1 describes a building panel with a core made of wood chips or wood fibers, which are glued and pressed together, and two covering layers on the upper side and on the side bottom consisting of scattered WPC material. The WPC core and cover layers are pressed together under heat so that the thermoplastic plastic materials of the WPC layers are bonded to the wood core. It was mentioned that the surface could be provided with a variety of coatings for building panels, but no specific surface layer was disclosed. Flexural strength can be increased and moisture movements can be reduced, but a conventional wood-based core layer in the intermediate parts such as wood particle board, HDF or OSB is not waterproof and will swell considerably if exposed to water that can penetrate the joints between panels to adjacent floors.
[0043] The document WO 2008/122668 A1 describes a method of manufacturing laminated floor panels comprising a WPC core, a base layer of paper or fiber fiber fused to the WPC core and a top laminate comprising at least one layer of paper impregnated with melamine resin, and being attached to the base layer through that impregnating material or a layer of plastic fused to a base layer of fiberglass. This base layer can provide a lamination between the core and surface of the laminate. However, a thermosetting laminate layer will shrink and swell more than a WPC core and panels will warp at low and high relative humidity, and the surface or glue layer may crack or peel.
[0044] WO 2012/053036 A1 describes a floor comprising a layer of base material of LVT and a single sheet of WPC laminated over the LVT. An adhesive layer is provided between the LVT layer and the WPC layer and a non-woven fabric is embedded in the adhesive layer.
[0045] A disadvantage is that the lower part of the panel comprises a layer of soft LVT and this part must be used to form the locking system. The snap resistance will be low especially when the temperature rises due to direct sun exposure during summer or when floor heating is used.
[0046] EP 2402155 A1 shows a floor panel with a WPC layer and a reinforcement layer. The reinforcement layer is intended to minimize the dimensional variations of the WPC layer. The reinforcement layer is incorporated into the WPC layer so that portions of the WPC layer extend on both sides of the reinforcement layer. The floor panel includes a high pressure laminate construction comprising at least one printed decorative layer and an impregnated protective overlay pressed together with heat and pressure. Alternatively, the WPC layer can be provided with a polymeric film having a decoration pattern, which is printed on the film. The polymeric film can be fused to the WPC layer. Other alternatives are wood veneer layers and vulcanized cellulose layers.
[0047] The reinforcing layer can increase the possibilities of bonding a thermosetting laminate to a thermoplastic core, but it will not eliminate the problems related to different moisture movements of a thermosetting top layer connected to a thermoplastic core.
[0048] WO 2009/065769 (Valinge) describes that a panel can be formed by a powder mixture of wood fibers and binders. Thermosetting binders can be used in the core and thermoplastic binders in the surface layer or vice versa.
[0049] WO 2011/129757 (Valinge) describes a digitally printed surface layer which may comprise a thermoplastic material, for example vinyl, applied in powder form on a substrate. The powder layers may comprise a mixture of wood fibers, thermosetting binders in powder form and powdered thermoplastic particles. It is also described that a powder-based surface layer comprising thermoplastic particles can be applied over a core, preferably of plastic or wood, which can comprise one or several layers of different densities. An LVT floor panel can be produced with a powder-based surface layer and digitally printed.
[0050] US 2003/0008130 describes a water resistant wood particle board comprising wood particles, thermosetting resins and resin particles of a thermoplastic resin. The wood particle board comprises thermoplastic sheet material on the upper side and on the underside. Wood particles and thermoplastic particles have an average particle diameter of 1-2 mm. The average particle size of the outer layers is smaller than the particle size of the middle layer.
[0051] The three applications above do not offer a solution for the bonding and moisture movements of a surface layer comprising thermosetting binders laminated to a core comprising thermoplastic material.
[0052] As a summary, it can be mentioned that none of the methods described above can be used to achieve a considerable improvement in the surface properties, stability and cost structures of a thermoplastic-based floor intended to be installed floating with a system of strong fit. Objectives and Summary
[0053] A general objective of at least certain embodiments of the invention is to offer a building panel based on thermoplastics which has better surface properties and more favorable cost structure than known types of building panels.
[0054] A first specific objective of at least certain embodiments of the invention is to offer a panel, preferably a building panel, with a core comprising thermoplastic material, which gives the panel improved water-resistant properties, and a surface comprising thermosetting resins that give the panel improved surface properties. The core and surface must be such that a strong bond can be achieved with heat and pressure and such that moisture movements of the materials in the core and surface are adapted to reduce warping and high shear forces.
[0055] A second specific objective of at least certain embodiments of the invention is to form a board material that can be used as a core in such panels.
[0056] A third specific objective of at least certain embodiments of the invention is to adapt the core so that a strong interlocking system can be formed in such floor panels.
[0057] The embodiments of the invention are based on the understanding that conventional plastic and wood composite materials such as WPC are mainly adapted for construction purposes where high loads must be handled for a long period of time in outdoor environments. Performance optimization was aimed at high bond strengths between wood fibers and plastic material, UV light stability, flexural strengths, deformation under load and the like. Various additives are included, such as coupling agents that increase the bond between the wood particles and the thermoplastic material and UV stabilizers that neutralize color changes. A mixture of wood particles and thermoplastic particles is melted under pressure to form wood/plastic pellet composites that provide a high quality homogeneous panel after pressing or extrusion.
[0058] Such optimization is not suitable for floating floor applications where the panel is arranged on a support subfloor indoors and is covered by a protective surface layer. In fact it offers an unnecessarily high cost structure and the material properties can cause major problems related to the possibility of applying a surface layer comprising thermosetting resins especially if direct lamination based on a hot-hot pressing step is used. No attempt has yet been made to form a board that is adapted to provide a strong locking system.
[0059] The embodiments of the invention are based on a second understanding that the material properties of the core and preferably also of the surface layer must be changed relative to conventional technology in order to form a panel that has all the favorable core properties of types for floors based on thermoplastics, but also the favorable surface properties for floors based on laminate and wood dust where the top layer comprises a high content of melamine formaldehyde resins. In general terms, this means that a core comprising thermoplastic material must be adjusted so that it has a performance more similar to that of a layer formed by thermosetting resins. It is preferable that the surface layer comprising thermosetting resins is adjusted so that it behaves more like a thermoplastic material.
[0060] According to a first aspect of the invention, a method for producing a building panel is offered. The method comprises the steps of:
[0061] offer a core forming a mat-shaped layer comprising a dry mixture of wood particles in powder form and thermoplastic particles in powder form, heat and cool the mat-shaped layer under pressure so that a sheet is formed after pressing;
[0062] apply a surface layer comprising a powder mixture comprising wood particles and thermosetting resin on the core, and;
[0063] to laminate the powder-based surface layer in a hot-hot pressing operation to the core and thereby form a building panel, where the wood particles of the surface layer and the core are bonded together by resin thermosetting cured.
[0064] The sheet formed after pressing can be flat.
[0065] The surface layer may further comprise thermoplastic material. The thermoplastic material can be located between the bonded wood particles. The thermoplastic material can comprise thermoplastic particles. In particular, the thermoplastic material may comprise molten thermoplastic particles. Thermoplastic particles can be comprised in the powder mixture.
[0066] The formation of a board from a dry mix and mixing of the thermosetting particles in the surface layer will increase the core moisture movement, decrease the surface layer moisture movement and improve the bonding properties so that it is possible do a direct lamination in a hot-hot press operation from the surface layer to the core.
[0067] The thermosetting resin can be an amino resin such as a melamine formaldehyde resin, a urea formaldehyde resin, a phenol formaldehyde resin, or a combination thereof.
[0068] The thermoplastic particles of the dry blend may comprise polyvinyl chloride (PVC), polypropylene (PP) or polyethylene (PE).
[0069] The thermoplastic particles of the dry mix can have an average particle size of about 0.3 mm or less.
[0070] The surface layer can be applied as two layers arranged on top of each other and the top layer of the two layers can comprise bleached fibers and thermosetting particles. The bleached fibers can be bleached cellulose fibers.
[0071] The core wood particles may, prior to application, be dried to a moisture content of about 2% or less.
[0072] The core wood particles may, prior to application, be sieved to an average size of 1.0 mm or less.
[0073] The content of the wood particles in the core can vary in the range of about 30 - 80% by weight.
[0074] The core can be formed with a pressure that is less than 2MPa (20 bar).
[0075] The thermoplastic material may be comprised in the powder mixture of the surface layer and may comprise thermoplastic particles. Furthermore, thermoplastic particles can have an average size of about 0.2 mm or less.
[0076] The surface layer wood particles may be smaller than the core wood particles.
[0077] The core may comprise an intermediate layer and a top layer. The intermediate layer may comprise a higher amount of thermoplastic material than the upper layer.
[0078] The intermediate layer may further comprise limestone particles.
[0079] The surface layer may comprise a transparent wear layer comprising thermosetting resins, wear resistant particles such as aluminum oxide particles, and cellulose fibers, preferably bleached cellulose fibers.
[0080] The wood fibers of the core and/or surface layer can be cellulose fibers, such as bleached cellulose fibers.
[0081] The thermosetting resin of the transparent wear layer can be an amine resin such as a melamine formaldehyde resin, a urea formaldehyde resin, a phenol formaldehyde resin, or a combination thereof.
[0082] According to a second aspect of the invention, a building panel comprising a core and a surface layer is provided. The core comprises a mixture of thermoplastic material and wood particles. The surface layer comprises a composite material comprising wood particles bonded together by a cured thermosetting resin. The surface layer is bonded to the core by the cured thermosetting resin.
[0083] The surface layer may comprise a composite material comprising individual thermoplastic particles spaced apart and surrounded by wood particles bonded together by a cured thermosetting resin.
[0084] The surface layer can be bonded to the core by molten thermoplastic particles and cured thermosetting resins.
[0085] The thermosetting resin can be an amino resin such as a melamine formaldehyde resin, a urea formaldehyde resin, a phenol formaldehyde resin, or a combination thereof.
[0086] The thermoplastic core material may comprise PVC, PP or PE.
[0087] The surface layer may comprise thermoplastic particles with a size of about 0.2 mm or less.
[0088] The surface layer may comprise wood particles with an average size that is less than the average size of the core wood particles.
[0089] The building panel can be a floor panel.
[0090] A pair of opposing edges can be formed with a mechanical locking system comprising a protruding strip. Furthermore, the protruding strip may comprise wood particles and thermoplastic material.
[0091] According to a third aspect of the invention, there is offered a building panel having a core, a surface layer and two opposing edges comprising a mechanical locking system. The building panel comprises a tongue and groove for vertical snapping and a protruding strip with a snapping element on one edge cooperating with a snapping groove on another edge for horizontal snapping. The core is formed from three layers of materials. Each layer comprises thermoplastic materials and fillers. An upper layer and a lower layer comprise wood particle fillers and an intermediate layer comprises mineral particle fillers.
[0092] The snap element can be formed in the lower layer. Furthermore, the protruding strip and the locking element can be formed in the lower layer. Additionally, the protruding strip, the locking element and the locking groove can be formed in the lower layer.
[0093] The locking element and the locking groove can be formed in the lower layer.
[0094] The building panel can be a floor panel.
[0095] The building panel may comprise a surface layer comprising wood particles and thermosetting resins.
[0096] The principles of embodiments of the invention can be used to form a board that can be used as a core in building panels, especially building panels comprising a surface layer with thermosetting resins that is directly laminated to the core. The surface of the board is adapted to such lamination as a considerable amount of free wood fibers is exposed on the surface and can be bonded with the cured thermoplastic resins of the surface layer.
[0097] According to a fourth aspect of the invention, a board is provided. The board comprises an upper surface, a lower surface, and an intermediate portion located between the upper surface and the lower surface. The intermediate portion comprises wood particles embedded in a thermoplastic material. The upper surface essentially comprises raw wood particles adapted to bond with a thermosetting resin.
[0098] On the upper surface, essentially rough wood particles may protrude beyond the upper surface.
[0099] The thermoplastic material may comprise PVC, PP or PE.
[00100] The average size of wood particles on the upper surface can range from about 0.1 - 1.0 mm.
[00101] On the bottom surface, wood particles can protrude beyond the bottom surface. Brief Description of Drawings
[00102] Modalities of the invention will be described below along with the modalities and in more detail with reference to the attached exemplary drawings, where:
[00103] Figures 1a-d illustrate a board and a panel with a core of such board material, a surface layer and a balancing layer;
[00104] Figures 2a-h illustrate the board material produced by dry blends and thermoplastic compounds;
[00105] Figures 3a-d illustrate production methods for forming boards and panels;
[00106] Figures 4a-4d illustrate floor panels with a snap system. Detailed Description
[00107] Figure 1a shows a cross section of a board 1' according to a preferred embodiment of the invention. The board 1' is formed by a dry mix comprising a mixture of thermoplastic particles in powder form and wood particles 20 in powder form which is pressed at high temperature. The thermoplastic particles melt and form a thermoplastic material 21 which binds the wood particles 20 together. By dry mixing is meant a preferably uniform product comprising a dry mixture of at least two different and separate materials in particle form which are preferably distributed random in the matrix. Individual materials can aggregate, for example, due to vibration or material flow when forces act on individual particles.
[00108] The dry mix is preferably applied as a layer of dry powder onto a lower belt of a continuous press, heated and cooled under pressure. The powder is pressed as a dry mix and not as a preformed plastic compound in pellet form. By plastic compound is meant a preferably uniform product comprising a mixture of materials where at least one of the materials is in a molten state during mixing. The individual materials in a plastic composite particle cannot separate after mixing due, for example, to vibration.
[00109] Pressing parameters such as pressure, pressing time, pressing and cooling temperatures, are adapted so that the production method can offer a board material that, compared to a conventional WPC board, is sufficiently water resistant so that it can be used as a core in a water resistant floor panel, but it may have a higher moisture movement and may comprise wood particles 20 in the top 11 and in the bottom 12 that are not completely covered by a plastic material 21 and which can be bonded to other fibers with a thermosetting resin when a fiber-based surface layer is applied.
[00110] A board 1' can be formed with an intermediate portion 13 comprising wood particles 20 embedded in a thermoplastic material 21 and with the upper part 11 preferably comprising wood particles 20 which are not essentially covered by molten plastic particles and which may project slightly over the thermoplastic material 21 after pressing. By rough wood particles is meant a wood particle having at least a portion of the surface comprising wood material which is not covered by another material, for example a thermoplastic material. Preferably the lower part 12 comprises similar roughwood particles 20 protruding from beneath the thermoplastic material 21. The roughwood particles 20 in the upper 11 and lower 12 are adapted so that they can be used to facilitate a strong bond between core and separate layers comprising, for example, a thermosetting resin such as melamine formaldehyde resin which during lamination with heat and pressure can penetrate rough wood particles. The board 1' can be formed with a porosity that provides a suitable moisture movement adapted to the moisture movement of a surface layer comprising, for example, a thermosetting resin.
[00111] As a non-limiting example we can mention that the dry mix can be preheated to about 80-120°C, for example about 100°C before pressing, pressed to about 0.5 to 1.5 MPa (5-15 bar), for example, about 10 bar in a heating zone at a temperature of about 130-200°C, for example, about 160°C and cooled to 50-100°C, for example , about 80°C under pressure in a cooling zone. The pressing time in the heating zone can be about 1-3 minutes, for example about 2 minutes, for a board that is about 4-5 mm thick.
[00112] The dry mix may, for example, comprise 40-60% by weight (% by weight), for example 48% by weight PVC powder (eg Vestolit 6507) with a particle size of about 0 .08-0.2 mm, for example 0.1 mm, 40-60% by weight, for example 48% by weight, of wood particles in powder form with an average length of about 0.5- 2 mm, for example about 1 mm, and preferably 1-10% by weight, for example 4% by weight, of colored pigments. A wood-plastic particle board hereinafter referred to as a WPP board can be formed more economically.
[00113] The WPP board is preferably 3 - 12 mm thick and the dry spread mixture is preferably compressed to about 25 - 30% of its original thickness giving a rigid board with a preferred density of about 1100 - 1300 kg/ m3. An even more preferred range of thicknesses for a board material intended to be used as a core for floating floor panels in domestic environments ranges from about 3 - 6 mm and such board is preferably formed from a dry mix having a thickness , after spreading but pressing, about 1 - 2 cm.
[00114] Various thermoplastic materials that are available in powder form can be used, such as, for example, polyvinyl chloride (PVC), polypropylene (PP) and polyethylene (PE) and they can be mixed. The moisture content of the wood particles preferably ranges from 1 - 2% but moisture contents preferably up to about 6% can also be used. Wood particles can comprise individual fibers or several fibers connected to each other. The particle thickness is preferably less than the particle length. The average length L of the wood particles preferably ranges from 0.1 - 1.0 mm. The particles can also comprise cellulose fibers which can be bleached cellulose fibers.
[00115] The dry mix is preferably spread over a belt as a mat-shaped layer and the spread forms the desired thickness. The dry mix can also be applied as a thick layer leveled to the desired belt thickness with a ruler that removes excess material.
[00116] It is preferable to use wood particles with low moisture content, preferably 2% or less, especially when the WPP panel in a second production step is used as a core that laminates directly in a hot-hot pressing operation with a layer comprising thermosetting resins. A high moisture content creates water vapor that can cause surface defects such as locally delaminated portions on the surface.
[00117] An optimization of the size and content of wood particles, pressure, time and pressing temperature can be used to form a board with desired properties. For example, small, well-defined particles with an average size of less than 1.0 mm, a high resin content >50% by weight, high pressure around 40-60 bar, longer pressing time and high pressing temperature up to 180 - 190°C will improve the water resistance and weather stability of a WPP panel. Disadvantages are that density and material cost will increase and it will become more difficult to bond a surface layer comprising thermosetting resins to the WPP board. Consequently, there are some limitations that must be considered when the objective is to form a low cost panel with appropriate properties that can be combined with surface layers comprising thermosetting resins.
[00118] The fluctuation of thermoplastic particles increases when the melting temperature is increased from, for example, 160 to 200°C. Wood particles will change color at an elevated temperature of about 190°C and properties will deteriorate considerably above 200°C. A high pressure, for example, 30 - 40 bar and even a pressure of 60 bar and more high combined with a high temperature, eg 190°C will provide a very homogeneous and moisture stable high density material with high mechanical strengths. These board materials may, for example, be suitable for construction purposes, outdoor use and for floors with very high water resistance, but generally may not be the most preferred solutions when the board is intended for use as a core in a moisture resistant floating floor for indoor use with a moisture sensitive surface layer comprising thermosetting resins. Therefore, in some applications, instead low pressures around 5 - 20 bar and pressing temperatures of 160 - 180°C may be preferred as this will reduce the density and buoyancy of the molten thermoplastic particles. In some applications it is also possible to produce the board with a low pressure of just a few bar.
[00119] It is possible to form a panel with a porous microstructure with properties that provide adequate moisture movement and a base for direct lamination of a surface comprising thermosetting resins.
[00120] The pressing time in relation to the thickness of the board is also important. Long press times will create more fluctuation than shorter press times. Thicker boards require quite a long pressing time until a suitable temperature is reached in the middle section of the board. A long press time can damage the plastic material in the top and bottom parts near the press tables that are exposed to higher temperatures for longer periods of time than in the middle section. A thicker board of, for example, 6 mm can be produced as two 3 mm boards that are fused together with heat and pressure.
[00121] A high starting temperature can considerably reduce the pressing time. For example, the pressing time of a 4mm board at 160°C can be reduced from 4 minutes to 2 minutes if the dry mix is preheated to 100°C before pressing. A preferred preheat ranges from 80 - 120°C. Naturally, higher temperatures up to, for example, 150°C can be used. The dry mix is preferably pre-pressed prior to preheating and/or final pressing so that most of the air between the particles is removed.
[00122] A WPP board is, preferably before the pressing step, formed with several layers comprising different material compositions. The middle part of the core 5 which preferably comprises about 60% or more of the thickness of the core may, for example, be formed from a dry mixture comprising 40-60% by weight, for example 50% by weight, of particles. of wood and 40-60% by weight, for example 50% by weight, of thermoplastic particles. This can provide high water resistance. The dry mixture in the upper and lower portions of the core 5 may comprise, for example, 50-70% by weight, for example 60% by weight, of wood particles and 30-50% by weight, for example, 40% by weight. weight, of thermoplastic particles and this can provide a high bond strength between the core 6 and a surface layer 4 comprising thermosetting resins.
[00123] The thermoplastic particles of the dry mix melt during pressing and form a plastic material that at least partially surrounds the wood particles. In particular, the plastic material can completely enclose the wood particles. All of the parameters described above are preferably adapted to the type and size of thermoplastic particles that are used as they may have different melting temperatures and flotation properties.
[00124] A WPP board can have very favorable properties. For example, a board with 40-60% by weight, for example 50%, PVC powder and 40-60% by weight, for example 50%, softwood virgin wood dust such as, for example , spruce or pine is waterproof and the thickness increase after 24 hours in water can be about 3-5%, for example about 4%. This could be compared to conventional HDF which swells 16% and WPC which swells 2%.
[00125] Moisture movement along the board, as the relative humidity RH ranges from 20% to 90%, can be around 0.1 - 0.2% compared to 0.4% for HDF and 0.05 % and lower for WPC.
[00126] The content of wood particles may preferably range between 20 - 80% by weight and even more preferably between 40 - 60% by weight. Small wood particles sieved through a 0.3 mm mesh and small thermoplastic particles sieved through a 100 mesh provide, after pressing, a more homogeneous board than, for example, larger wood or thermoplastic particles in the 0.6 range mm for wood particles and 200 microns for thermoplastic particles. This can be used together with the pressing parameters described above to optimize the moisture movements and the bonding properties of the board to various other layers applied over the top 11 and/or the bottom 12.
[00127] The entire board 1’ can be spread out in one operation. The board can also be spread as a multi-layer board where several layers are applied on top of each other preferably with different material compositions. The size and material properties of the particles and the mixture between thermoplastic particles and wood particles can vary in layers.
[00128] The board can be used as a floor panel without any additional decorative surface layers. Pigments can be enough to create a decoration. In some applications just a protective lacquer may be sufficient. Wear resistant particles can be included in the top 11 of the board. Prints, preferably fingerprints, applied directly onto the WPP board or onto an intermediate plastic sheet preferably covered by a protective lacquer, such as, for example, a UV light curable lacquer and/or a transparent thermoplastic sheet can also be used .
[00129] One advantage is that the properties of the fiber structure at the top 11 form a printed layer so that a digital print, preferably a water-based digital inkjet print comprising pigment dispersions, can be applied with casting reduced ink droplet or even no ink droplet leakage, which is often the case when water-based ink drops are applied to a non-absorbent thermoplastic surface.
[00130] The Binder and Powder (BAP) printing method can also be used to provide a digital print on the board. A liquid binder, commonly called "ink white", comprising, for example, water and viscosity-increasing substances, such as, for example, glycol, is applied by a Piezo printhead in a predefined pattern over the part. top 11 of core 5. Dyes, commonly called "dry paint", comprising for example wood fibers and colored pigments are applied over the liquid pattern. Some dyes are bound by the digitally formed liquid ink white pattern. Other unbound dry ink type dyes are removed and the remaining bound dyes form a digital decoration. This two-step process can be repeated and multiple colors of dry ink can be applied so that an advanced high definition multi-color digital print can be formed at reduced cost. The main advantage is that the wood fibers at the top of the board reduce or eliminate uncontrolled fluctuation of the ink white droplets and a high quality BAP print can be obtained on a board comprising non-absorbent thermoplastic material.
[00131] In some applications it is preferable to use cellulose fibers bleached at the top 11 of the core 5. Such fibers can improve print quality when conventional direct printing technologies or digital printing technologies are used. The bleached cellulose fibers can comprise colored pigments which can be used to form a base color for printing.
[00132] Wood particles can be combined with other fillers, for example, mineral fillers such as stone dust, quartz sand, clayey materials, feldspathic fluxes, chalk, limestone and the like. Plasticizers and foaming agents can also be included in the dry mix. Some of the materials can be included as composite pellets or powder produced by plastic composites. A preferred dry mix is a mix comprising wood particles mixed with mineral particles such as, for example, limestone, and this can be used to increase water resistance. It is possible to use a higher amount of lime in the middle section than in the upper and lower sections of the board. The middle section can comprise wood/limestone fillers and the top and bottom sections can comprise wood fillers only. The intermediate section may, for example, comprise a mixture of about 40-60% by weight, for example, 50% by weight, of thermoplastic particles, 20-40% by weight, for example, 30% by weight, of limestone. and 10-30% by weight, for example 20% by weight, of wood particles.
[00133] Materials based on recycled fiber such as, for example, particles comprising recycled carpets, nylon fibers, packaging material or textile fibers, can also be used as fillers. Packaging materials comprising laminated layers of wood fiber material and thermoplastic material are especially suitable as a filler as they can comprise 10 - 20% thermoplastic material which can be used as a binder.
[00134] All of the fillers mentioned above can be used in some applications to partially or completely replace wood particles in separate layers of the board or on the entire board.
[00135] The board 1’ can be cut and the edges can be formed by conventional rotating tools. Scraping or notching can also be used, preferably combined with increased temperature. Dust and shavings from machining and scraping can be recycled and mixed into the dry mix.
[00136] Figure 1b shows a panel 1 according to a preferred embodiment of the invention where an upper surface layer 4 and a lower balance layer 6 comprising wood particles 20 and thermosetting resins are laminated to a core 5 comprising a WPP board 1' as described above. Preferably the surface layer 4 and preferably also the balancing layer 6 are directly laminated under heat and pressure in a separate hot-hot production process to produce a preformed core 5 . This two-stage production method offers the advantages that the pressing parameters can be optimized for the formation of the board material that constitutes the core 5 and for the lamination of the surface and balance layers to the core. Preferably the board is cooled to room temperature and stored for several days before the final lamination of the surface and balance layers.
[00137] The core 5, the surface layer 4 and the balancing layer 6 can also be produced in a one-step operation with a continuous or discontinuous pressing operation which is preferably a hot-cold process. A one-step hot-hot process can also be used.
[00138] The thermosetting resin in the surface layer 4 and in the balance layer 6 can be a melamine formaldehyde, urea formaldehyde or phenol formaldehyde resin, or a mixture of these resins. The resins are preferably applied in dry powder form. Alternatively, the wood particles can be impregnated with liquid resins and dried. Preferably, thermoplastic particles 21a can be included in the surface layer 4 and the balance layer 6 in order to increase the bond between the core 5 and the surface layer 4 and to reduce moisture movements and shrinkage forces during production and production. cooling to room temperature.
[00139] Preferably, the surface layer 4 comprises a decorative wear layer 3 which is spread over the WPP core. The decorative wear layer 3 may comprise, for example, a powder mixture of 300-500 g/m2, for example 400 g/m2, of 25-45% by weight, for example 36% by weight, of particles of melamine formaldehyde, 20-40% by weight, eg 30% by weight, PVC powder, 15-35% by weight, eg 25% by weight, wood fibers, 4-10% by weight for example 7% by weight of aluminum oxide 22 and 1-3% by weight, for example 2% by weight of colored pigments. The PVC powder can be a raw PVC powder without any additives such as, for example, PVC in emulsion (Vestolit 6507) with a particle size of 0.1 - 0.2 mm or PVC in emulsion (Vestolit P 1353K) with a particle size of about 0.04 - 0.06 mm. A small particle size generally gives a higher quality as small PVC particles give a more homogeneous material structure. It is preferable to use larger thermoplastic particles in core 5 than in surface layer 4. Preferably, thermoplastic particles that are used to form core 5 have an average size that is greater than about 0.10 mm, and thermoplastic particles that are used to form the surface layer have an average size that is less than about 0.10 mm.
[00140] The dry mix that is used to form the balance layer which is preferably also spread over the WPP board comprises in this preferred embodiment a powder of about 100-300 g/m2, for example 200 g/m2, comprising a mixture of 25-45% by weight, for example 35% by weight, melamine, 2545% by weight, for example 35% by weight, wood fibers and 20-40% by weight, for example 30 % by weight of PVC powder.
[00141] Powder layers are preferably applied in two steps. The balancing layer 6 in a first step is spread over the WPP core 5 and stabilized by spraying with water so that the melamine powder melts. The wet powder surface is heated with IR light so that a hard but uncured powder surface is formed allowing the WPP board to be turned over with the spread surface facing down. The wear-resistant decorative layer 3 is then spread over the top of the WPP core 5 and the decorative powder layer is stabilized in the same way as the balancing layer 6.
[00142] The powder layers 3, 6 are then directly laminated to the WPP core in a hot-hot pressing operation where, for example, a pressure of 3-5MPa (30-50) bar, for example, 4MPa (40 bar) can be applied for 10-30 seconds, for example 20 seconds, at a temperature of 130-200°C, for example 160°C. Preferably the cured surface layer 4 and the cured balance layer 6 comprise individual thermoplastic particles 21a spaced apart and surrounded by wood particles 20 bonded together by the thermosetting resin. The surface layer 4 and the balancing layer 6 are preferably bonded to the core 5 by cured thermosetting resins and preferably also by molten thermoplastic particles 21 which fuse together when cooled to room temperature after heating under pressure.
[00143] The pressure of direct lamination can be considerably decreased even in the case where deep domed surfaces are formed as the thermoplastic core becomes softer when heated during lamination and creates a more uniform back pressure than, for example, HDF. Convex structures with a depth of about 0.5 mm and greater can be formed with a direct rolling pressure of about 2MPa (20 bar) and even lower.
[00144] The layers have been considerably modified compared to known technology in order to allow a direct lamination of a surface layer 4 comprising thermosetting resins to a core 5 comprising thermoplastic material. Modifications were made based on the following principles.
[00145] The moisture movements of the WPP core material have been increased considerably compared to a conventional WPC board in order to allow handling of the moisture movements of the surface layer comprising a thermosetting resin. This was done with a core that is based on a dry blend of wood fibers and thermoplastic powder and which after pressing obtains material properties that allow moisture to penetrate the core under high humidity conditions and evaporate under dry conditions.
[00146] Preferably, moisture movement and shrinkage during pressing and cooling to ambient temperatures of the powder-based surface layer comprising thermosetting resins and wood fibers have been reduced and layer flexibility has been increased, for example, by inclusion of thermoplastic particles in the powder layer. Thermosetting resins in powder form and thermoplastic powder particles can be combined if they are mixed with wood fibers that bond to both types of plastic.
[00147] The WPP core is adapted in such a way that a surface layer can be directly laminated to the core with hot-hot process. The formation of a core from a dry mixture of small wood particles in powder form and thermoplastic particles in powder form creates a matrix material when pressed together with heat which comprises a considerable amount of uncoated fibers free in the surface portions of the core that can be used to provide a strong bond of a surface layer comprising thermosetting resins to a core comprising thermoplastic material.
[00148] A disadvantage may be that the upper part of the exposed cured surface layer comprises small thermoplastic particles 21a which may be more sensitive to staining than the greater part of the exposed surface which comprises melamine/cured wood fiber material. The melted small thermoplastic particles 21a can also form small bumps on the main surface when the press table is opened after lamination. Such small bumps can be removed with a brushing operation when the surface cools.
[00149] Figure 1c shows that, as an alternative, the thermoplastic particles 21a in the decorative surface layer 3 can be covered with a transparent wear layer 2 without thermoplastic particles. This transparent wear layer 2 may be a powder overlay, preferably comprising melamine formaldehyde resins and cellulose fibers, preferably bleached cellulose fibers 20c. The powder overlay may also comprise colored pigments and/or aluminum oxide particles 22. A powder overlay mixture may, for example, comprise 6085% by weight, eg 72.5% by weight, melamine formaldehyde resins, 50-30% by weight, for example 22.5% by weight, of transparent cellulose fibres, and 2-8% by weight, for example, 5% by weight of aluminum oxide particles. This powder overcoat 2 can be very thin, for example around 50 - 100 g/m2 and will have no major effect on shrinkage forces during pressing and moisture movement. The stain resistance will be superior to that of most thermoplastic surfaces. It is of course possible to include small thermoplastic particles in the overlay and the stain resistance will be marginally affected especially if the particles are small and the content is low. The clear overcoat 2 can also be applied directly to the core 5. Alternatively, the clear wear layer 2 can be a backing paper. A UV lacquer can also be used as a protective layer.
[00150] Preferably, different types of fibers and particle sizes can be used in the different layers. The average size of the wood fibers or particles 20a in the core 5 is preferably greater than the average size of the fibers 20b in the decorative wear layer 3. The transparent wear layer 2 preferably comprises bleached cellulose fibers 20c and the core 5 and the layer. of decorative wear 3 preferably comprises opaque fibers 20a, 20b. The content of the plastic particles in the core 5 can vary. It is possible to use a higher content of thermoplastic particles, for example, in the middle parts of the core 5 than in the outer parts of the core and the fiber content in the outer parts of the core can be higher in the middle parts of the core. This will facilitate a strong bonding of the surface layer 4 and the balance layer 6 during direct lamination when thermosetting resins float and penetrate the wood fibers of the wood particles on the outer parts of the core 5.
[00151] A floor panel according to an embodiment of the invention is preferably characterized by the fact that the content of the thermoplastic material is higher in the core 5 than in the decorative wear layer 3. The content of thermoplastic particles in the surface layer 4 may also vary and be higher in a lower layer near the core 5 than in an upper layer near the outermost surface portion.
[00152] A surface layer 4 which comprises only thermosetting resins and wood fibers and no thermoplastic particles can also be directly laminated to a WPP core. Moisture movement of surface layer 4 and core 5 can be adapted so that delamination is prevented. For example, the surface layer may comprise urea formaldehyde resin which is less sensitive to moisture than melamine formaldehyde resins.
[00153] Figure 1d shows a floor panel 1 that can have the same surface layer 4 and the same balance layer 6 as those described above and shown in figures 1b and 1c. The surface layer 4 may also comprise a fingerprint 19 applied over the powder-based decorative layer 4 preferably comprising a base color. The digital print 19 can also be applied onto a paper layer 18, comprising a base color and incorporated into the decorative powder layer. The paper layer can also be a printed paper impregnated with a melamine resin. Alternatively, the paper 18 is not impregnated and is located between the upper and lower powder layers comprising a thermosetting resin. Impregnation and bonding takes place automatically during pressing when liquid melamine resins from the lower decorative powder layer and the upper powder overlay 2 penetrate into the paper fibers. The powder overcoat 2 can be replaced by a conventional melamine impregnated overcoat. PU coating and/or clear plastic sheets can also be used as a protective top layer.
[00154] The core 5 comprises an upper part 5a and a lower part 5c which is a WPP material described above and one or more intermediate layers 5b. The intermediate layer is preferably a layer of mineral-plastic particles (MPP) which comprises a mixture of thermoplastic material and mineral fillers, eg limestone. This layer can instead be elastic and soft, especially if plasticizers are used, and can provide noise dampening and softness to the floor. The intermediate layer is preferably spread as a dry mixture, comprising thermoplastic particles in powder form and minerals in powder form, when the core 5 is formed in the same way as the upper layer 5a and the lower layer 5c. The intermediate layer can also be produced in a separate step according to conventional methods used to form the known LVT layers and can be bonded to the spread layers with heat and pressure. The intermediate layer and other core layers can also comprise a mixture of minerals, wood fibers and thermoplastic particles. Chalk, powdered talc, limestone and cork particles can, for example, be used as fillers. Very thin layers, eg 0.1 - 0.5 mm or 0.2 - 1.0 mm, may be sufficient to improve the sound properties and flexibility of the panel.
[00155] A wide range of recycled wood particles and mineral particles can be used in all core layers and such materials can be mixed with each other. It is preferable to use HDF residues or wood particle board residues or similar wood residues which comprise binders and which are not suitable for burning due to environmental considerations. Replaced old laminate floors can be crushed into small particles and used as filler.
[00156] WPP board can be replaced by other core materials, for example HDF boards and mineral boards, in all embodiments of the invention. A mixture of wood fibers, thermosetting particles, thermoplastic particles, pigments and wear resistant particles with or without a powder overlay as described above can be used as a surface layer. This offers several advantages over conventional technology. Shrinkage during production and moisture movements will be reduced. Thinner balance layers can be used. It is also more economical to replace, for example, melamine with thermoplastic particles.
[00157] Figure 2a shows plastic compounds 23 in the form of pellets that were produced, for example, by an extruder. The plastic composite 23 comprises wood particles 20 which have been mixed with a thermoplastic material 21 under heat and pressure until a homogeneous mixture results. Such thermoplastic composites 23 are used to form a wood-plastic composite board or a so-called WPC board 40 as shown in Figure 2b. The board 40 and its upper part 11 and lower part 13 comprise a homogeneous mixture of wood particles 20 and thermoplastic material 21 and practically all wood particles are embedded in the thermoplastic material.
[00158] Figure 2c shows a dry mixture 25 of thermoplastic particles 21a in powder form and wood particles 20 in powder form. The average length L of the wood particles 20 is preferably about 1.0 mm or less. Thermoplastic particles 21a are preferably even smaller and can have a size of about 0.1 - 0.2 mm. Figure 2d shows that a wood-plastic particle board 41 or a WPP board is formed when the dry mix 25 is pressed under heat. The dry mix 25 forms a material structure that is not completely homogeneous and this allows the wood fibers of the wood particles 20 to contract and swell slightly at a different moisture. There may be a sufficient amount of wood fibers in the top 11 and bottom 13 of the WPP board that are not completely covered by the thermoplastic material 21 and this provides a strong bond between the WPP board and a surface layer when heat and pressure are applied to a surface layer which may comprise thermosetting particles or thermoplastic and thermosetting particles mixed with wood fibers. The wood particles 20 in the upper part 11 of the board 41 and preferably also in the lower part 13 of the board may project slightly over or under the molten thermoplastic material 21 when the pressure of the board formation is released.
[00159] Figures 2e-2h show a similar formation of a layer or board material as discussed above with reference to Figures 2a-d. In this preferred embodiment, wood particles 20 have been replaced by mineral particles 24. A mineral-plastic composite (MPC) board 42 is formed when a plastic composite 23 comprising mineral particles 24 is used as the raw material as shown in Figure 2e and in Figure 2f. A plastic-mineral particle board 43 is formed when a dry mix 25 comprising mineral particles 24 is used as the raw material as shown in Figure 2g and Figure 2h.
[00160] Figure 3a shows a production equipment and a production method that can be used to form a panel from a dry mixture of thermoplastic particles and fillers such as wood particles or mineral particles according to the described modalities above. A dry mix 25 is applied by a spreading unit 33 onto a lower belt 31, pressed through a 2-roller calender and heated in a preheat zone 35. The hot dry mix is then pressed between the lower belt 31 and the top belt 32 at an elevated temperature in a pressing and heating zone 36 for the thermoplastic particles to melt. The molten powder is then sized to the desired thickness by interval rollers 37 and cooled under pressure in a pressing and heating zone 38 to the desired outlet temperature for, for example, a wood-plastic particle board 41 or a mineral-plastic particle board 43 is formed. The dry mix can comprise a mixture of different fillers, for example wood particles and mineral particles.
The wood particle board 41 or mineral particle board 43 may comprise one or several layers individually produced as described above which can be fused together under heat and pressure to form a thicker multilayer board. Preferably, the individual layers can have a thickness of about 1-3 mm.
[00162] It is possible to form a board with a very low pressure, for example a few bars. Improved quality can be achieved with higher pressures, eg 0.5-1MPa (5 - 10 bar).
[00163] The production can comprise two continuous presses. A press can be a hot press and a press can be a cold press. The advantage is that it is not necessary to heat the upper belt 32 or the lower belt 31.
[00164] A WPP board can also be produced with a hot-hot pressing operation in continuous or batch presses. Pressureless cooling increases the porosity of the board. The internal bond strength and water resistance will generally be lower than for similar boards produced with a hot-cold pressing operation. This can be compensated for with a higher content of thermoplastic particles.
[00165] Figure 3b shows an extruder and a production method for forming a layer comprising thermoplastic particles and fillers. A hopper 27 is filled with thermoplastic particles 21a and fillers, eg mineral fillers 24 or wood fillers 20 and the particles are mixed to specification and loaded into the feed section of the extruder. Material is fed through one or two screws, melted and mixed into a homogeneous mixture by a combination of heat and shear forces. From the tip of the screw, the material is filtered and pressed through a flat sheet die 29 which provides a paste of essentially the same width and thickness as the finished layer. Die 29 has adjustable die nozzles 9 generally controlled by oil temperature.
[00166] The melted slurry is further processed with a 3-roller polishing calender 30 comprising a fixed central hot roller and two adjustable rollers on each side for final sizing of a layer that can be used as a core layer 5a, 5b, 5c or as a surface layer 4 in a floor panel according to the invention. A board may comprise several layers, which are formed as board material of WPP, WPC and MPC as described above.
[00167] The extruder can be used to produce plastic compounds in the form of pellets.
[00168] Figure 3c shows that separate layers, eg a core layer 5, dry blends 25 and decorative foils 17 can be formed and laminated together in a continuous hot-cold pressing operation. The pressing steps described in figures 3a and 3c can be combined in a continuous production line with downstream cooling and annealing equipment.
[00169] Figure 3d shows a batch press 44 that can be used to apply a surface layer 3 and a balancing layer 6 comprising thermosetting resins, wood particles and preferably thermoplastic particles to a core 5 comprising thermoplastic particles and fillers, preferably fillers wooden. Application is preferably done with a hot-hot pressing method.
[00170] Figures 4a and 4b show a floor panel 1 with a locking system comprising a tongue 10 and a groove 9 for vertical locking and a protruding strip 7 with a locking element 8 on a first edge 1b that cooperates with a snap groove 14 on a second adjacent edge 1a and snap the edges in a horizontal direction. Tongue 10 may be formed on the second edge comprising an engagement groove as shown in Figure 4a. Tongue 10 may also be formed over the first edge comprising strip 7 (not shown). The tongue groove 9 can also be formed over the first or second edge. The panel has a core 5 with an upper layer 5a and a lower layer 5c each comprising wood particles mixed with thermoplastic material and an intermediate layer 5b preferably comprising mineral particles and thermoplastic material. Intermediate layer 5b is preferably softer than upper layer 5a and lower layer 5c and can be used to provide noise dampening. The strip 7, the locking element 8 and the locking groove 14 are formed in the rigid lower layer 5c.
[00171] The intermediate layer 5b can be formed as a separate layer and can be laminated between the upper and lower layers which can be applied as a dry mix before pressing. Intermediate layer 5b can also be applied as a dry mix as shown in Figure 4b.
[00172] Figure 4c shows an embodiment in which the intermediate layer 5b comprises a higher thermoplastic material content and a lower fiber content than an upper layer 5a and a lower layer 5c. Such a core can be formed with, for example, increased stiffness and moisture resistance and this could be combined with a direct lamination of the surface layer 4 and the balancing layer 6 which is made against layers comprising a higher fiber content.
[00173] Figure 4d shows an embodiment in which a softer layer 5b, preferably comprising thermoplastic material mixed with wood and/or mineral fibers is applied to an upper part of core 5, preferably above tongue 10 and groove 9. Such a core provides increased noise damping.
[00174] A batch of separate layers and materials can be included in the core, eg glass fibers or metal foil. Blades, eg aluminum foil, can improve heat distribution when floor heating is used in the subfloor. Blades that provide heat can also be incorporated into the core. EXAMPLE
[00175] 48% by weight of wood particles and dry spruce fibers, with a moisture content of about 1% and sieved through a 400 micron mesh, were mixed with 48% by weight of PVC particles (Vestolit 1353 ) with an average size of 60 microns and with 4% by weight of gray colored pigments so a dry mixture of wood particles in powder form and thermoplastic particles in powder form was obtained. The dry mixture was then applied as a 12 mm thick powder coat onto a 0.6 mm aluminum sheet, preheated in a hot air furnace to 100°C and taken to a hydraulic press. The dry mixture was pressed for 2 minutes at a value of 160°C and a pressure of 1 MPa (10 bar) and cooled. The press was opened when the temperature reached 80°C. A flat and rigid 4 mm gray wood-plastic particle board (WPP) was obtained at room temperature.
[00176] A 200 g/m2 balance layer of powder comprising a mixture of 35% by weight melamine, 35% by weight wood fibers and 30% by weight PVC powder (Vestolit 1353) was spread over the WPP board, sprayed with water and dried with an IR lamp so that the mixture was bonded to the WPP board allowing the board to be turned upside down with the dry uncured balance layer pointing downwards.
[00177] A wear-resistant decorative surface layer of 400 g/m2 with a light brown base color was then spread over the upper side of the WPP core. The decorative wear layer comprised a powder blend of 36% by weight melamine formaldehyde particles, 30% by weight raw PVC powder (Vestolit P 1353K) with a particle size of about 0.04 - 0.06 mm, 25% by weight of recycled wood fibers/wood particles, 7% by weight of aluminum oxide and 2% by weight of colored pigments.
[00178] A water-based paint comprising 30% water-based pigment dispersions and 70% glycol, water and acrylic binder was injected with a digital Piezo ink head in the powder and a wood grain decoration was formed .
[00179] A 50 g/m2 powder overcoat mixture comprising 72.5% by weight of melamine resins, 22.5% by weight of bleached cellulose fibers, and 5% by weight of aluminum oxide particles was spread over the fingerprint. The powder overlay was sprayed with water-based microdrops comprising a release agent and dried with an IR lamp to prevent an "expulsion" of powder during the pressing operation.
[00180] The WPP board with the decorative surface and the balancing layer was pressed in a conventional direct lamination hot-hot press under a heat of 160°C and a pressure of 2 MPa (20 bar) for 20 seconds until forming a floor blank with a waterproof core comprising thermoplastic material and a smudge and wear resistant digitally printed surface layer comprising a thermosetting resin.
[00181] The floor blank was, after cooling to room temperature, cut into panels for individual floors and the edges were formed with a slanted snapping system on the long edges and a folding system on the short edges comprising a separate flexible tongue that allows snapping with vertical offset, tilt and horizontal snapping.

权利要求:
Claims (15)
[0001]
1. Method for producing a building panel (1), characterized in that it comprises: • providing a core (5) forming a mat-shaped layer comprising a dry mixture (25) of raw wood particles (20) in powder form and thermoplastic particles (21a) in powder form, heating and cooling the mat-shaped layer under pressure so that a sheet is formed after pressing; • applying a surface layer (4) comprising a powder mixture comprising wood particles (20) and thermosetting resin onto the core (5); • laminate the powder-based surface layer (4) in a hot-hot pressing operation or a hot-cold pressing operation to the core (5) and thereby form a building panel (1), where the particles The wood (20) of the surface layer (4) and the core (5) are bonded together by the cured thermosetting resin.
[0002]
2. Method according to claim 1, characterized in that the surface layer (4) comprises a thermoplastic material (21).
[0003]
3. Method according to claim 1 or 2, characterized in that the thermosetting resin is an amine resin such as a melamine formaldehyde resin, a urea formaldehyde resin, a phenol formaldehyde resin, or a combination thereof.
[0004]
4. Method according to any one of claims 1 to 3, characterized in that the thermoplastic particles (21a) of the dry mixture (25) comprise polyvinyl chloride (PVC), polypropylene (PP), or polyethylene (PE ).
[0005]
5. Method according to any one of the preceding claims, characterized in that the thermoplastic particles (21a) of the dry mix (25) have an average particle size of about 0.3 mm or less.
[0006]
6. Method according to any of the preceding claims, characterized in that the surface layer (4) is applied as two layers (3, 2) arranged one on the other and where an upper layer (2) of said two layers (3, 2) comprises bleached cellulose fibers and thermosetting particles.
[0007]
7. Method according to any one of the preceding claims, characterized in that the wood particles (20) of the core (5), before providing the core, are dried to a moisture content of about 2% or less .
[0008]
8. Method according to any one of the preceding claims, characterized in that the wood particles (20) of the core (5) before application are sieved to an average size of 1.0 mm or less.
[0009]
9. Method according to any one of the preceding claims, characterized in that the content of wood particles (20) in the core (5) varies in the range from about 30 to 80% by weight.
[0010]
10. Method according to any one of the preceding claims, characterized in that the core (5) is formed with a pressure less than 20 bar.
[0011]
11. Method according to any one of claims 2 to 10, characterized in that the thermoplastic material (21) is comprised in the powder mixture of the surface layer (4) and comprises thermoplastic particles (21a), in which the thermoplastic particles they have an average size of about 0.2 mm or less.
[0012]
12. Method according to any of the preceding claims, characterized in that the wood particles (20) of the surface layer (4) are smaller than the wood particles (20) of the core (5).
[0013]
13. Method according to any one of the preceding claims, characterized in that the core (5) comprises an intermediate layer (5b) and an upper layer (5a), wherein the intermediate layer (5b) comprises a quantity of material thermoplastic (21) larger than the top layer (5a).
[0014]
14. Method according to any one of the preceding claims, characterized in that the surface layer (4) comprises a transparent wear layer (2) comprising a thermosetting resin, wear-resistant particles such as aluminum oxide particles ( 22), and cellulose fibers, preferably bleached cellulose fibers (20).
[0015]
15. Method according to claim 14, characterized in that the thermosetting resin of the transparent wear layer (2) is an amine resin such as a melamine formaldehyde resin, a urea formaldehyde resin, a phenol resin formaldehyde, or a combination thereof.

类似技术:

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公开号 | 公开日 | 专利标题

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BR112016021957B1|2021-08-17|METHOD FOR PRODUCING A BUILDING PANEL

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EP3126145A4|2017-11-29|

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BR112016021957A2|2017-08-15|

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EP3126145B1|2020-08-26|

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EP3126145A1|2017-02-08|

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US20190248108A1|2019-08-15|

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法律状态:
2019-12-24| B06U| Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette]|

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2021-06-29| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|

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2021-07-20| B350| Update of information on the portal [chapter 15.35 patent gazette]|

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2021-08-03| B350| Update of information on the portal [chapter 15.35 patent gazette]|

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2021-08-17| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 30/03/2015, OBSERVADAS AS CONDICOES LEGAIS. |

优先权:

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申请号 | 申请日 | 专利标题

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SE1450382-5|2014-03-31|

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SE1450382|2014-03-31|

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PCT/SE2015/050380|WO2015152802A1|2014-03-31|2015-03-30|Composite boards and panels|

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